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Similar cyclization reactions occur in monoterpene biosynthesis from geranyl pyrophosphate, but are not oxidative. [5] THCA synthase exhibits no catalytic activity against cannabigerol, which lacks a carboxyl group compared to CBGA, suggesting that the carboxyl group of CBGA is necessary for the reaction to occur. [1]
By heat. CBD heated to 175, [13] or 250–300 °C may partially be converted into THC. [14] Even at room temperature, trace amounts of THC can be formed as a contaminant in CBD stored for long periods in the presence of moisture and carbon dioxide in the air, with storage under inert gas required to maintain analytically pure CBD.
Tetrahydrocannabinolic acid (THCA, 2-COOH-THC; conjugate base tetrahydrocannabinolate) is a precursor of tetrahydrocannabinol (THC), an active component of cannabis. [1]THCA is found in variable quantities in fresh, undried cannabis, but is progressively decarboxylated to THC with drying, and especially under intense heating such as when cannabis is smoked or cooked into cannabis edibles.
Comparison of phytocannabinoids. Cannabinoids (/ kəˈnæbənɔɪdzˌ ˈkænəbənɔɪdz /) are compounds found in the cannabis plant or synthetic compounds that can interact with the endocannabinoid system. [1][2] The most notable cannabinoid is the phytocannabinoid tetrahydrocannabinol (THC) (Delta-9-THC), the primary intoxicating compound in ...
US: Schedule II as Syndros, and Schedule III as Marinol [2] Schedule I delta-9 tetrahydrocannabinol in pure form. Tetrahydrocannabinol (THC) is a cannabinoid found in cannabis. [9] It is the principal psychoactive constituent of cannabis and one of at least 113 total cannabinoids identified on the plant.
Δ-8-tetrahydrocannabinol (delta-8-THC, [a] Δ 8-THC) is a psychoactive cannabinoid found in the Cannabis plant. [1] It is an isomer of delta-9-tetrahydrocannabinol (delta-9-THC, Δ 9-THC), the compound commonly known as THC, with which it co-occurs in hemp; natural quantities of ∆ 8-THC found in hemp are low.
nazarov-cyclization. RSC ontology ID. RXNO:0000209. The Nazarov cyclization reaction (often referred to as simply the Nazarov cyclization) is a chemical reaction used in organic chemistry for the synthesis of cyclopentenones. The reaction is typically divided into classical and modern variants, depending on the reagents and substrates employed.
In organic chemistry, an electrocyclic reaction is a type of pericyclic rearrangement where the net result is one pi bond being converted into one sigma bond or vice versa. [1] These reactions are usually categorized by the following criteria: Reactions can be either photochemical or thermal. Reactions can be either ring-opening or ring-closing ...